采用气相色谱(GC-ECD)及田间试验方法,研究氰戊菊酯在香蕉及蕉园土壤中的残留降解动态。结果表明,氰戊菊酯在香蕉上的原始残留沉积量因不同施药处理有所差异,香蕉及蕉园土壤上的降解速度较缓慢,降解规律符合“C=C0·e-kt”一级动力学关系。在香蕉上,相关系数r = 0.9722~0.9980(P<0.01),降解系数k = 0.0703~0.0767,半衰期T1/2 = 9.1~9.9 d,降解99%所需要时间T0.99 = 60.1~65.6 d;在土壤中,k = 0.0821,T1/2 = 8.5 d,T0.99 = 56.1 d。距第2次施药后62~68 d,最终香蕉的残留量<0.01 mg·kg-1,土壤中为0.015~0.020 mg·kg-1。在福建蕉区,氰戊菊酯的常规施药方法是间隔期7 d连续2次施用有效剂量112.50 g·hm-2,采样前安全间隔期可推荐为>13.6 d,产品质量最终可符合GB/T 2763-2012、NY/T 750-2011的要求。
The residue dynamics of fenvalerate in bananas and the soil were studied by using the methods of GC and field experiments. The results showed that the original sediment of fenvalerate in bananas was significant differences among different treatments. Fenvalerate was degrading at a slow rate in bananas and its soil. The residual degradation dynamics of fenvalerate degradation in bananas and its orchard soil could be followed first order kinetic equation ‘C=C0·e-kt’. In bananas, the correlation coefficient (r) ranged from 0.9722 to 0.9980 (P < 0.01), the degradation coefficient (k) ranged from 0.0703 to 0.0767, T1/2 ranged from 9.1 d to 9.9 d and T0.99 ranged from 60.1 d to 65.6 d. On the other hand, r=0.9877 (P<0.01), k=0.0821, T1/2=8.5 d and T0.99=56.1 d in its soil. Furthermore, after fenvalerate secondly being applied for 62—68 d, the residue of fenvalerate in banana was < 0.01 mg·kg-1, and that in orchard soil was from 0.015 to 0.020 mg·kg-1. The application of fenvalerate into bananas is done according to the regular method in Fujian with an effective dose of 112.50 g·hm-2, and applied twice with an interval of 7 d which means that >13.6 d can be recommended as pre-harvest time. The quality safety of their products was fulfilled quality requirements of GB/T 2763-2012 and NY/T 750-2011.
[1] 张敏恒.新编农药商品手册[M]. 北京: 化学工业出版社, 2006: 449.
[2] 葛志荣.日本肯定列表制度食品中农业化学品残留量(药品卷)[M]. 北京: 中国标准出版社, 2006.
[3] 中华人民共和国卫生部, 中华人民共和国农业部.中华人民共和国国家标准[S]. GB/T 2763-2012, 食品安全国家标准 食品中农药最大残留限量, 2012.
[4] 中华人民共和国农业部. 绿色食品标准[S]. NY/T750-2011 绿色食品热带、亚热带水果, 2011.
[5] 文礼章,陈永年,潘桐,龚道新.氰戊菊酯在烟叶上的残留动态研究[J]. 农药, 1990,29(1): 9—12.
[6] 吴萍,施海燕,王鸣华.氰戊菊酯、乐果在小麦上的残留分析[J]. 江苏农业科学, 2008( 2): 248—250.
[7] 袁玉伟,司朝光,林桓,王静.毒死蜱、氰戊菊酯和高效氯氰菊酯在甘蓝中的残留动态研究[J]. 农业环境科学学报, 2008,27(3): 1199—1202.
[8] 杨燕涛,殷春杭,丁晓莉,钱允辉. 高效氯氰菊酯、氰戊菊酯与毒死蜱在扁豆上残留动态[J]. 安徽农学通报, 2006 (9): 158—159.
[9] 杨燕涛,殷春杭,丁晓莉,钱允辉.毒死蜱、氯氰菊酯和氰戊菊酯在小白菜上的残留研究[J]. 江苏农业科学, 2007(1): 202—204.
[10] 张涛,姜瑞德,王文娇,王继青,程星.高效氯氰菊酯、氰戊菊酯和三唑酮农药在黄瓜上的残留动态研究[J]. 山东农业科学, 2009(9): 51—53.
[11] 李辉,张玉亭,郭永泽,邵辉,刘磊,宋淑荣.20%敌畏?氰戊乳油在桃中的残留消解动态研究[J]. 天津农业科学, 2009,15(2): 71—74.
[12] 马庆华,续九如,王贵禧,姚立新,吕兆林.冬枣百菌清、氯氰菊酯和氰戊菊酯残留的研究[J]. 中国农学通报, 2009,25(15): 5l—54.
[13] 中华人民共和国农业部. 中华人民共和国农业行业标准[S]. NY/T788-2004, 农药残留试验准则, 2004.
[14] 中华人民共和国农业部.中华人民共和国农业行业标准[S]. NY/T 761-2004, 蔬菜和水果中有机磷、有机氯、拟除虫菊酯和氨基甲酸酯类农药多残留的测定, 2004.
[15] 中华人民共和国国家质量监督检验检疫总局. 中华人民共和国国家标准[S]. GB/T14550-2003, 土壤中六六六和滴滴涕测定的气相色谱法, 2003.